In the aftermath of a great and terrible war, Haruka finds herself the last surviving human on Earth. Though humanity may have been wiped out, she is not entirely alone. Advanced robots have survived the apocalypse, and Haruka lives with five who care for her: Spike, a boyish android who is very attached to her; Trigger, hot-tempered with a penchant for firearms; Cleric, the intelligent problem solver; Reeves, whose thoughtfulness overshadows his intimidating appearance; and Angela, a sword wielding recluse with an aversion towards humans. Residing in a high-rise building at the center of the city, Haruka lives a relatively peaceful life with her mechanical family. However, her life is far from a stable one. Not only is a lack of resources a concern, but violent, remnant robots from the war roam free, ready to destroy whomever they meet. Kurogane Communication follows Haruka as she tries to survive in an apocalyptic world while facing many dangers that will challenge her daily life.

The story begins in Anpanman World, where everybody is bustling around, getting ready for the annual Star Festival. On that day, an egg emerges from Baikinman's garbage box, and when it hatches, a mysterious boy named Kurun emerges from within. Though Kurun does not know where he came from, he spends his days having fun with everybody. But one day, black stars begin raining down. Anpanman thinks that something suspicious might be occurring at the Star of Life, and he heads there.

As a young boy, Xu-Xian is forced to free his pet, a small snake. Unbeknownst to him, the snake is actually a young snake goddess named Bai-Niang and she is in love with him. Many years later, when they are both adults, the princess is magically transformed into a human and sets out to find her love. But the local wizard believes her to be a vampire, and banishes Xu-Xian from the village in order to save him. Xu-Xian's pet pandas Panda and Mimi set out to save him and bring him, in the process becoming leaders of an animal gang.

Following the popularity of the original omnibus OVA, this release offers 4 more stories but in animation only.